Cyclization/hydrosilylation of functionalized diynes catalyzed by a cationic platinum phenanthroline complex

被引：43
作者：
Madine, JW [1 ]
Wang, X [1 ]
Widenhoefer, RA [1 ]
机构：
[1] Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 03期
关键词：
D O I：
10.1021/ol006901u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] A 1:1 mixture of the platinum phenanthroline complex (phen)PtMe2 and B(C6F5)(3) catalyzed the cyclization/hydrosilylation of functionalized 1,6-and 1,7-diynes to form silylated 1,2-dialkylidenecycloalkanes in good yield and with high Z-selectivity.
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页码：385 / 388
页数：4
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