The Pt(II)-catalyzed Baeyer-Villiger oxidation of cyclohexanone with H2O2 in ionic liquids

被引：45
作者：
Conte, V
Floris, B
Galloni, P
Mirruzzo, V
Scarso, A
Sordi, D
Strukul, G
机构：
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy
[2] Univ Venice, Dipartimento Chim, I-30123 Venice, Italy
来源：
GREEN CHEMISTRY | 2005年 / 7卷 / 05期
关键词：
D O I：
10.1039/b416923a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Pt(II)-catalyzed Baeyer-Villiger oxidation of cyclohexanone with H2O2 in a two-phase system, H2O-IL, is a viable procedure, characterized by synthetically interesting yields, better than those of the same reaction in H2O-halogenated solvents.
引用
收藏
页码：262 / 266
页数：5
相关论文
共 71 条
[1]   Use of Ionic Liquids for the Diels-Alder Reaction of Oleochemicals [J].
Behr, A. ;
Naendrup, F. ;
Nave, S. .
ENGINEERING IN LIFE SCIENCES, 2003, 3 (08) :325-327
[2]  
Berkessel A, 2002, ANGEW CHEM INT EDIT, V41, P4481, DOI 10.1002/1521-3773(20021202)41:23<4481::AID-ANIE4481>3.0.CO
[3]  
2-7
[4]   CH3ReO3/H2O2 in room temperature ionic liquids:: an homogeneous recyclable catalytic system for the Baeyer-Villiger reaction [J].
Bernini, R ;
Coratti, A ;
Fabrizi, G ;
Goggiamani, A .
TETRAHEDRON LETTERS, 2003, 44 (50) :8991-8994
[5]   FRIEDEL CRAFTS REACTIONS IN AMBIENT-TEMPERATURE MOLTEN-SALTS [J].
BOON, JA ;
LEVISKY, JA ;
PFLUG, JL ;
WILKES, JS .
JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (04) :480-483
[6]   Sustainable epoxidation of electron-poor Olefins with hydrogen peroxide in ionic liquids and recovery of the products with Supercritical CO2 [J].
Bortolini, O ;
Campestrini, S ;
Conte, V ;
Fantin, G ;
Fogagnolo, M ;
Maietti, S .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (24) :4804-4809
[7]   Epoxidation of electrophilic alkenes in ionic liquids [J].
Bortolini, O ;
Conte, V ;
Chiappe, C ;
Fantin, G ;
Fogagnolo, M ;
Maietti, S .
GREEN CHEMISTRY, 2002, 4 (02) :94-96
[8]  
Brunetta A, 2004, EUR J INORG CHEM, P1030
[9]  
Cammarata L, 2001, PHYS CHEM CHEM PHYS, V3, P5192, DOI 10.1039/b106900d
[10]   Biotransformation of cyclohexanone using immobilized Geotrichum candidum NCYC49 -: Factors affecting the selectivity of the process [J].
Carballeira, JD ;
Alvarez, E ;
Sinisterra, JV .
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2004, 28 (01) :25-32
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