Synthesis of mixed ligand and pillared paddlewheel MOFs using waste polyethylene terephthalate material as sustainable ligand source

被引：22

作者：

Raja, Duraisamy Senthil ^{[1
]}

Pan, Chih-Chiung ^{[1
]}

Chen, Chia-Wei ^{[1
]}

Kang, Yu-Hao ^{[3
]}

Chen, Jiun-Jen ^{[3
]}

Lin, Chia-Her ^{[1
,2
]}

机构：

[1] Chung Yuan Christian Univ, Dept Chem, Taoyuan 320, Taiwan

[2] Chung Yuan Christian Univ, R&D Ctr Membrane Technol, Taoyuan 320, Taiwan

[3] Ind Technol Res Inst, Green Energy & Environm Res Labs, Hsinchu 310, Taiwan

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2016年 / 231卷

关键词：

Microporous material; Metal-organic framework; Solvothermal synthesis; Renewable resources; DABCO; METAL-ORGANIC FRAMEWORKS; POROUS COORDINATION POLYMER; PRESSURE METHANE ADSORPTION; GAS SORPTION PROPERTIES; RATIONAL DESIGN; SEPARATION; SITES; NETS;

D O I：

10.1016/j.micromeso.2016.05.035

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of five isostructural pillared-paddlewheel MOFs, [M-2(BDC)(2)(DABCO)] (1-5), (where M = Fe(II) (1), Co(II) (2), Ni(II) (3), Cu(II) (4) and Zn(II) (5); BDC = benzene-1,4-dicarboxylate; and DABCO = 1,4-diazabicyclo[2.2.2]octane) have been synthesized by using waste polyethylene terephthalate (PET) material as a direct BDC source. The optimal reaction condition has been achieved for all the MOFs with 100% depolymerization of waste PET material in the reaction. The synthesized MOFs have been characterized using powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analyses, and N-2 gas sorption measurements. Results showed that the porous MOFs have similar properties of their corresponding literature reports. (C) 2016 Elsevier Inc. All rights reserved.

引用

页码：186 / 191

页数：6

共 34 条

[21] Enhanced gas sorption properties of a new sulfone functionalized aluminum metal-organic framework: Synthesis, characterization, and DFT studies [J].