A SnO2-Based Cathode Catalyst for Lithium-Air Batteries

被引:35
作者
Mei, Delong [1 ]
Yuan, Xianxia [1 ]
Ma, Zhong [1 ,4 ]
Wei, Ping [2 ]
Yu, Xuebin [3 ]
Yang, Jun [1 ]
Ma, Zi-Feng [1 ]
机构
[1] Shanghai Jiao Tong Univ, Dept Chem Engn, Shanghai 200240, Peoples R China
[2] Nanning Univ, Sch Mech Elect & Qual Technol Engn, Nanning 532999, Guangxi, Peoples R China
[3] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
[4] Brookhaven Natl Lab, Energy & Photon Sci Directorate, Upton, NY 11973 USA
基金
中国国家自然科学基金;
关键词
tin dioxide; carbon coated tin dioxide; cathode catalyst; microstructure; Li-air batteries; EFFICIENT ELECTROCATALYST; SNO2; NANOPARTICLES; LI-O-2; BATTERIES; CARBON; PERFORMANCE; NANOWIRES; COMPOSITE; NANOCOMPOSITE; GROWTH; POWER;
D O I
10.1021/acsami.6b02402
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SnO2 and SnO2@C have been successfully synthesized with a simple hydrothermal procedure combined with heat treatment, and their performance as cathode catalysts of Li-air batteries has been comparatively evaluated and discussed. The results show that both SnO2 and SnO2@C are capable of catalyzing oxygen reduction reactions (ORR) and oxygen evolution reactions (OER) at the cathode of Li-air batteries, but the battery with SnO2@C displays better performance due to its unique higher conductivity, larger surface area, complex pore distribution, and huge internal space.
引用
收藏
页码:12804 / 12811
页数:8
相关论文
共 48 条
  • [31] The double perovskite oxide Sr2CrMoO6-δ as an efficient electrocatalyst for rechargeable lithium air batteries
    Ma, Zhong
    Yuan, Xianxia
    Li, Lin
    Ma, Zi-Feng
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (94) : 14855 - 14858
  • [32] Influence of cathode process on the performance of lithium-air batteries
    Ma, Zhong
    Yuan, Xianxia
    Sha, Hao-Dong
    Ma, Zi-Feng
    Li, Qian
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (25) : 11004 - 11010
  • [33] Oh SH, 2012, NAT CHEM, V4, P1004, DOI [10.1038/NCHEM.1499, 10.1038/nchem.1499]
  • [34] Preparation and electrochemical properties of SnO2 nanowires for application in lithium-ion batteries
    Park, Min-Sik
    Wang, Guo-Xiu
    Kang, Yong-Mook
    Wexler, David
    Dou, Shi-Xue
    Liu, Hua-Kun
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (05) : 750 - 753
  • [35] Reduced Graphene Oxide-Polypyrrole Composite as a Catalyst for Oxygen Electrode of High Rate Rechargeable Li-O2 Cells
    Selvaraj, C.
    Kumar, Surender
    Munichandraiah, N.
    Scanlon, L. G.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (04) : A554 - A560
  • [36] Monodisperse CoFe2O4 nanoparticles supported on Vulcan XC-72: High performance electrode materials for lithium-air and lithium-ion batteries
    Sener, Tansel
    Kayhan, Emine
    Sevim, Melike
    Metin, Onder
    [J]. JOURNAL OF POWER SOURCES, 2015, 288 : 36 - 41
  • [37] Effects of cathode and electrolyte properties on lithium-air battery performance: Computational study
    Sergeev, Artem V.
    Chertovich, Alexander V.
    Itkis, Daniil M.
    Goodilin, Eugene A.
    Khokhlov, Alexei R.
    [J]. JOURNAL OF POWER SOURCES, 2015, 279 : 707 - 712
  • [38] Catalyst-free porous carbon cathode and ionic liquid for high efficiency, rechargeable Li/O2 battery
    Soavi, Francesca
    Monaco, Simone
    Mastragostino, Marina
    [J]. JOURNAL OF POWER SOURCES, 2013, 224 : 115 - 119
  • [39] A carbon powder-nanotube composite cathode for non-aqueous lithium-air batteries
    Tan, P.
    Shyy, W.
    Wei, Z. H.
    An, L.
    Zhao, T. S.
    [J]. ELECTROCHIMICA ACTA, 2014, 147 : 1 - 8
  • [40] Mesoporous α-MnO2/Pd catalyst air electrode for rechargeable lithium-air battery
    Thapa, Arjun Kumar
    Ishihara, Tatsumi
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (16) : 7016 - 7020