A SnO2-Based Cathode Catalyst for Lithium-Air Batteries

被引:35
作者
Mei, Delong [1 ]
Yuan, Xianxia [1 ]
Ma, Zhong [1 ,4 ]
Wei, Ping [2 ]
Yu, Xuebin [3 ]
Yang, Jun [1 ]
Ma, Zi-Feng [1 ]
机构
[1] Shanghai Jiao Tong Univ, Dept Chem Engn, Shanghai 200240, Peoples R China
[2] Nanning Univ, Sch Mech Elect & Qual Technol Engn, Nanning 532999, Guangxi, Peoples R China
[3] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
[4] Brookhaven Natl Lab, Energy & Photon Sci Directorate, Upton, NY 11973 USA
基金
中国国家自然科学基金;
关键词
tin dioxide; carbon coated tin dioxide; cathode catalyst; microstructure; Li-air batteries; EFFICIENT ELECTROCATALYST; SNO2; NANOPARTICLES; LI-O-2; BATTERIES; CARBON; PERFORMANCE; NANOWIRES; COMPOSITE; NANOCOMPOSITE; GROWTH; POWER;
D O I
10.1021/acsami.6b02402
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SnO2 and SnO2@C have been successfully synthesized with a simple hydrothermal procedure combined with heat treatment, and their performance as cathode catalysts of Li-air batteries has been comparatively evaluated and discussed. The results show that both SnO2 and SnO2@C are capable of catalyzing oxygen reduction reactions (ORR) and oxygen evolution reactions (OER) at the cathode of Li-air batteries, but the battery with SnO2@C displays better performance due to its unique higher conductivity, larger surface area, complex pore distribution, and huge internal space.
引用
收藏
页码:12804 / 12811
页数:8
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