Oxidation of closo-[B12Cl12]2- to the Radical Anion [B12Cl12]•- and to Neutral B12Cl12

被引：56

作者：

Boere, Rene T. ^{[3
]}

Kacprzak, Sylwia ^{[2
]}

Kessler, Mathias ^{[1
]}

Knapp, Carsten ^{[1
]}

Riebau, Rainer ^{[1
]}

Riedel, Sebastian ^{[1
]}

Roemmele, Tracey L. ^{[3
]}

Ruehle, Monika ^{[1
]}

Scherer, Harald ^{[1
]}

Weber, Stefan ^{[2
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Univ Freiburg, Inst Phys Chem, D-79104 Freiburg, Germany

[3] Univ Lethbridge, Dept Chem & Biochem, Lethbridge, AB T1K 3M4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

boron; cyclic voltammetry; Jahn-Teller distortions; oxidation; radical ions; CRYSTAL-STRUCTURE; BORON; BR; CL; HYPERCLOSO-B12H12; DERIVATIVES; CLUSTERS; SYSTEMS; CAGE;

D O I：

10.1002/anie.201004755

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Strong as an ox: Oxidation of the perchlorinated dodecaborate [B 12Cl12]2- by AsF5 in liquid sulfur dioxide leads to the Jahn-Teller-distorted radical anion [B12Cl 12]·- and to neutral B12Cl12 (see structure; B-brown, Cl-green). The formation of both compounds has been verified by a combination of several theoretical and experimental methods (pictured: cyclic voltammogram of [B12Cl12]2- in liquid SO2). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：549 / 552

页数：4

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