Facile synthesis of oligophenylene-substituted calix[4]arenes and their enhanced binding properties

被引:21
作者
Wong, MS [1 ]
Xia, PF
Zhang, XL
Lo, PK
Cheng, YK
Yeung, KT
Guo, XL
Shuang, SM
机构
[1] Hong Kong Baptist Univ, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Shanxi Univ, Inst Adv Chem, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
关键词
D O I
10.1021/jo048545p
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A facile and efficient protocol for the synthesis of oligophenylene OPP(n)-substituted calix[4]arenes (with n up to 4) via iodo-substituted oligoarylcalix[4]arenes has been developed. The cooperation effect of the proximate fluoroionophores in hexylsulfanyl end-capped OPP(n)-substituted calix[4]arene assemblies leads to metal ion binding enhancement.
引用
收藏
页码:2816 / 2819
页数:4
相关论文
共 52 条
[1]  
[Anonymous], 1998, ELECT MAT OLIGOMER A
[2]   Polyphenylene nanostructures [J].
Berresheim, AJ ;
Müller, M ;
Müllen, K .
CHEMICAL REVIEWS, 1999, 99 (07) :1747-1785
[3]   A biscalix[4]arene-based ditopic hard/soft receptor for K+/Ag+ complexation [J].
Budka, J ;
Lhoták, P ;
Stibor, I ;
Michlová, V ;
Sykora, J ;
Cisarová, I .
TETRAHEDRON LETTERS, 2002, 43 (15) :2857-2861
[4]  
Casnati A, 2001, CALIXARENES 2001, P365
[5]   A new Hg2+-selective chromoionophore based on calix[4]arenediazacrown ether [J].
Choi, MJ ;
Kim, MY ;
Chang, SK .
CHEMICAL COMMUNICATIONS, 2001, (17) :1664-1665
[6]  
de Namor AFD, 1998, CHEM REV, V98, P2495
[7]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[8]   SYNTHESIS AND STRUCTURAL STUDIES ON P-TERT-BUTYL-1,3-DIHYDROXY-2,4-DISULFANYLCALIX[4]ARENE AND ITS MERCURY COMPLEX [J].
DELAIGUE, X ;
HOSSEINI, MW ;
KYRITSAKAS, N ;
DECIAN, A ;
FISCHER, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) :609-610
[9]  
Fischer M, 1999, ANGEW CHEM INT EDIT, V38, P885, DOI 10.1002/(SICI)1521-3773(19990401)38:7<884::AID-ANIE884>3.0.CO
[10]  
2-K