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Effects of alloying elements on the corrosion behavior of Ni-based alloys in molten NaCl-KCl-MgCl2 salt at different temperatures
被引:102
作者:
Sun, Hua
[1
]
Zhang, Peng
[1
]
Wang, Jianqiang
[1
]
机构:
[1] Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jialuo Rd, Shanghai 201800, Peoples R China
关键词:
Ni-based alloy;
Molten chloride salt;
Corrosion;
Alloying element;
NICKEL;
SALTS;
COMPATIBILITY;
LICL;
ATMOSPHERES;
MECHANISMS;
RESISTANCE;
CHROMIUM;
METALS;
D O I:
10.1016/j.corsci.2018.08.021
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The effects of alloying elements on corrosion of Ni-based alloys in NaCl-KCl-MgCl2 under Ar in the temperature range of 600 similar to 800 degrees C were investigated by immersion test, SEM/EDS, EPMA and XRD techniques. A thermodynamic potential-pO(2-) diagram for Cr, Ni at 700 degrees C was constructed. The alloy corrosion is attributed to the dissolution of Cr to form Cr chlorides into salt. The elements Cr, Mo and W can affect the alloy corrosion. The corrosion is accelerated and the intergranular corrosion becomes more pronounced with temperature. Furthermore, the effects of the alloying elements on corrosion have a strong temperature dependence. The related mechanisms are discussed.
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页码:187 / 199
页数:13
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