Effects of alloying elements on the corrosion behavior of Ni-based alloys in molten NaCl-KCl-MgCl2 salt at different temperatures

被引:102
作者
Sun, Hua [1 ]
Zhang, Peng [1 ]
Wang, Jianqiang [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jialuo Rd, Shanghai 201800, Peoples R China
关键词
Ni-based alloy; Molten chloride salt; Corrosion; Alloying element; NICKEL; SALTS; COMPATIBILITY; LICL; ATMOSPHERES; MECHANISMS; RESISTANCE; CHROMIUM; METALS;
D O I
10.1016/j.corsci.2018.08.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effects of alloying elements on corrosion of Ni-based alloys in NaCl-KCl-MgCl2 under Ar in the temperature range of 600 similar to 800 degrees C were investigated by immersion test, SEM/EDS, EPMA and XRD techniques. A thermodynamic potential-pO(2-) diagram for Cr, Ni at 700 degrees C was constructed. The alloy corrosion is attributed to the dissolution of Cr to form Cr chlorides into salt. The elements Cr, Mo and W can affect the alloy corrosion. The corrosion is accelerated and the intergranular corrosion becomes more pronounced with temperature. Furthermore, the effects of the alloying elements on corrosion have a strong temperature dependence. The related mechanisms are discussed.
引用
收藏
页码:187 / 199
页数:13
相关论文
共 50 条
  • [31] Corrosion behavior of nickel-based superalloys in thermal storage medium of molten eutectic NaCl-MgCl2 in atmosphere
    Wang, Jun-wei
    Zhang, Cui-zhen
    Li, Zhuo-hua
    Zhou, Hong-xia
    He, Jia-xin
    Yu, Jing-chao
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2017, 164 : 146 - 155
  • [32] Corrosion behavior and mechanism of laser additive manufactured Ni-based alloy in CO2 environment at different temperatures and pressures
    Wang, Qinying
    Zhang, Xingshou
    Xiao, Meng
    Dong, Lijin
    Yang, Yi
    Xi, Yuchen
    Bai, Shulin
    Lin, Yuanhua
    [J]. MATERIALS TODAY COMMUNICATIONS, 2023, 35
  • [33] Corrosion of Two Iron-Based Aluminaforming Alloys in NaCl-MgCl2 Molten Salts at 600 °C
    Pellicot, Louis
    Gruet, Nathalie
    Serp, Jerome
    Malacarne, Romain
    Bosonnet, Sophie
    Martinelli, Laure
    [J]. MATERIALS, 2024, 17 (13)
  • [34] Intergranular corrosion of 316H stainless steel induced by SO42- ions in MgCl2-KCl-NaCl molten salt
    Ai, Hua
    Chen, Yanjun
    Yang, Xinmei
    Sun, Hua
    Su, Xingzhi
    Yan, Long
    Huang, Wei
    Gong, Yu
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2024, 271
  • [35] Evaluation of Corrosion Behavior of Various Fe- and Ni-Based Alloys in Molten Li2BeF4 (FLiBe)
    Sankar, Krishna Moorthi
    Keiser, James R.
    Sulejmanovic, Dino
    Lowe, Tracie M.
    Singh, Preet M.
    [J]. NUCLEAR TECHNOLOGY, 2024, 210 (03) : 391 - 408
  • [36] Corrosion performance of Ni-based structural alloys for applications in molten-salt based energy systems: Experiment & numerical validation
    Lee, M.
    Muransky, O.
    Karatchevtseva, I
    Huang, H.
    Laws, K. J.
    [J]. CORROSION SCIENCE, 2021, 190
  • [37] Accelerated corrosion of Ni-based alloys in molten chloride salts, due to Ni2Cr phase formation
    Teng, Fei
    Copeland-Johnson, Trishelle M.
    Tucker, Julie D.
    Cao, Guoping
    [J]. MATERIALIA, 2023, 31
  • [38] Effect of Salt Deposits on Corrosion Behavior of Ni-Based Alloys in Supercritical Water Oxidation of High-Salinity Organic Wastewater
    Li, Yanhui
    Wang, Shuzhong
    Yang, Jianqiao
    Zhang, Yan
    Xu, Donghai
    Guo, Yang
    [J]. JOURNAL OF ENVIRONMENTAL ENGINEERING, 2019, 145 (11)
  • [39] Corrosion of a Nickel-Based Alumina-Forming Alloy in Molten NaCl-MgCl2 at 600 °C For the Development of a Molten Salt Nuclear Reactor
    Pellicot, Louis
    Gruet, Nathalie
    Serp, Jerome
    Malacarne, Romain
    Bosonnet, Sophie
    Touze, Gaetan
    Grzonka, Justyna
    Martinelli, Laure
    [J]. HIGH TEMPERATURE CORROSION OF MATERIALS, 2024, 101 (05) : 1041 - 1054
  • [40] In-depth corrosion mechanisms of Fe- and Ni-based alloys in molten solar salt with varying extents of chloride and sulfate impurities
    Oskay, C.
    Gregoire, B.
    Meissner, T. M.
    Burek, B. O.
    Solimani, A.
    Galetz, M. C.
    [J]. CORROSION SCIENCE, 2025, 247