Synthesis of 1,5-Pentanediol by Hydrogenolysis of Furfuryl Alcohol over Ni-Y2O3 Composite Catalyst

被引：45

作者：

Wijaya, Husni Wahyu ^{[1
,2
]}

Kojima, Takashi ^{[1
]}

Hara, Takayoshi ^{[1
]}

Ichikuni, Nobuyuki ^{[1
]}

Shimazu, Shogo ^{[1
]}

机构：

[1] Chiba Univ, Dept Appl Chem & Biotechnol, Grad Sch Engn, Inage Ku, 1-33 Yayoi, Chiba 2638522, Japan

[2] Univ Negeri Malang, Dept Chem, Fac Math & Sci, State Univ Malang, Jl Semarang 5, Malang 65145, East Java, Indonesia

来源：

CHEMCATCHEM | 2017年 / 9卷 / 14期

关键词：

alcohols; biomass; hydrogenation; nickel; yttrium; NI/Y2O3; CATALYSTS; 1,2-PENTANEDIOL; HYDROGENATION; CONVERSION; ETHANOL; PHASE; Y2O3;

D O I：

10.1002/cctc.201700066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The addition of Y2O3 into Ni formed a composite catalyst that selectively produced 1,5-pentanediol rather than 1,2-pentanediol in the hydrogenolysis of furfuryl alcohol at 2.0 MPa H-2 and 423 K. Clearly, 1,5-pentanediol was produced over the Ni-0-Y2O3 boundary. This report highlights the properties of Ni-Y2O3, catalytic performance, and reaction route in the synthesis of 1,5-pentanediol from furfuryl alcohol.

引用

收藏

页码：2869 / 2874

页数：6

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