A new Vogel-like law: Ionic conductivity, dielectric relaxation, and viscosity near the glass transition

被引：77

作者：

Bendler, JT ^{[1
]}

Fontanella, JJ

Shlesinger, MF

机构：

[1] USN Acad, Dept Phys, Annapolis, MD 21402 USA

[2] Off Naval Res, Div Phys Sci, Arlington, VA 22217 USA

来源：

PHYSICAL REVIEW LETTERS | 2001年 / 87卷 / 19期

关键词：

D O I：

10.1103/PhysRevLett.87.195503

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A model is developed that describes temperature and pressure dependence of dielectric relaxation, ionic conductivity, and viscosity of glass-forming liquids near the glass transition temperature. The expressions for ionic conductivity are compared with experimental results for two polymer electrolytes. Those for dielectric relaxation are compared with data for poly(propylene oxide) and poly(vinyl acetate). The theoretical viscosity law is compared with experiment for propylene carbonate.

引用

页码：1 / 195503

页数：4

共 23 条

[11] EFFECT OF HIGH-PRESSURE ON ELECTRICAL RELAXATION IN POLY (PROPYLENE-OXIDE) AND ELECTRICAL-CONDUCTIVITY IN POLY(PROPYLENE OXIDE) COMPLEXED WITH LITHIUM-SALTS [J].

FONTANELLA, JJ ;

WINTERSGILL, MC ;

SMITH, MK ;

SEMANCIK, J ;

ANDEEN, CG .

JOURNAL OF APPLIED PHYSICS, 1986, 60 (08) :2665-2671

[12] APPLICATION OF THE BENDLER-SHLESINGER GENERALIZATION OF THE VOGEL EQUATION TO ION-CONDUCTING POLYMERS [J].

FONTANELLA, JJ ;

WINTERSGILL, MC ;

COUGHLIN, CS ;

MAZAUD, P ;

GREENBAUM, SG .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1991, 29 (06) :747-752

[13] Pressure and temperature variation of the electrical conductivity of poly(propylene glycol) containing LiCF3SO3 [J].

Fontanella, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (15) :7103-7109

[14] Dynamics in propylene carbonate and propylene carbonate containing LiPF6 [J].

Fontanella, JJ ;

Wintersgill, MC ;

Immel, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (11) :5392-5402

[15] Analysis of recent measurements of the viscosity of glasses [J].

Fulcher, GS .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1925, 8 (06) :339-355

[16] PVT RELATIONSHIPS FOR LIQUID AND GLASSY POLYVINYL ACETATE) [J].

MCKINNEY, JE ;

GOLDSTEIN, M .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1974, A 78 (03) :331-353

[17] DIELECTRIC-RELAXATION MEASUREMENTS OF POLYVINYL ACETATE) IN GLASSY STATE IN THE FREQUENCY-RANGE 10-6-106 HZ [J].

NOZAKI, R ;

MASHIMO, S .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (04) :2271-2277

[18] EFFECT OF PRESSURE ON GLASS TEMPERATURE AND DIELECTRIC RELAXATION TIME OF POLYVINYL ACETATE [J].

OREILLY, JM .

JOURNAL OF POLYMER SCIENCE, 1962, 57 (165) :429-&

[19] Dynamics of glass-forming liquids. V. On the link between molecular dynamics and configurational entropy [J].

Richert, R ;

Angell, CA .

JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (21) :9016-9026

[20]

Tammann G., 1926, Z ANORG ALLG CHEM, V156, P245, DOI DOI 10.1002/ZAAC.19261560121

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