Enzymatic Electrosynthesis of Alkanes by Bioelectrocatalytic Decarbonylation of Fatty Aldehydes

被引：24

作者：

Abdellaoui, Sofiene ^{[1
]}

Macazo, Florika C. ^{[1
]}

Cai, Rong ^{[1
]}

De lacey, Antonio L. ^{[2
]}

Pita, Marcos ^{[2
]}

Minteer, Shelley D. ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, 315 S 1400 E, Salt Lake City, UT 84112 USA

[2] CSIC, Inst Catalisis & Petroleoquim, C Marie Curie 2,L10, E-28049 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 09期

关键词：

aldehyde-deformylating oxygenases; aldehydes; alkanes; bioelectrochemical catalysis; enzymatic electrosynthesis; DEFORMYLATING OXYGENASE; CYANOBACTERIAL; BIOSYNTHESIS; FORMATE;

D O I：

10.1002/anie.201712890

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An enzymatic electrosynthesis system was created by combining an aldehyde deformylating oxygenase (ADO) from cyanobacteria that catalyzes the decarbonylation of fatty aldehydes to alkanes and formic acid with an electrochemical interface. This system is able to produce a range of alkanes (octane to propane) from aldehydes and alcohols. The combination of this bioelectrochemical system with a hydrogenase bioanode yields a H-2/heptanal enzymatic fuel cell (EFC) able to simultaneously generate electrical energy with a maximum current density of 25 mu A cm(-2) at 0.6 V and produce hexane with a faradaic efficiency of 24%.

引用

页码：2404 / 2408

页数：5

共 24 条

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