Avoid the PCB, mistakes: A more sustainable future for ionic liquids

被引:58
作者
Chatel, Gregory [1 ]
Naffrechoux, Emmanuel [1 ]
Draye, Micheline [1 ]
机构
[1] Univ Savoie Mt Blanc, LCME, Campus Savoie Technolac, F-73376 Le Bourget Du Lac, France
关键词
Environmental chemistry; Ionic liquids; Polychlorinated biphenyls; Sustainable chemistry; Toxicity; LCA; POLYCHLORINATED-BIPHENYLS PCBS; ACTIVE PHARMACEUTICAL INGREDIENTS; NON-HODGKIN-LYMPHOMA; THERMAL-STABILITY; MOLTEN-SALTS; IMIDAZOLIUM; SOLVENTS; VAPORIZATION; DEGRADATION; WATER;
D O I
10.1016/j.jhazmat.2016.11.060
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Based on our original knowledge and experience on both polychlorinated biphenyls (PCBs) identificatidn in aquatic ecosystems, and use of ionic liquids (ILs) as solvents and/or co-catalysts in green chemistry, we drawn a dared comparison between these two families. Indeed, PCBs has been used during several decades for their new properties, but are now considered as prevalent and persistent pollutants; some toxic effects on environment or human are still revealed. ILs, often designated as "green solvents" are increasingly used in numerous applications, but few studies reported about their environmental impact are still controversial. Through a parallel between properties and applications of PCBs and ILs, we wondered if history could not repeat itself, and how to provide a better future for ILs. Here, we provide some interesting comparisons and we discuss which tracks it could be important to follow for ILs applications in order to avoid the errors done with PCBs. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:773 / 780
页数:8
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