Ruthenium as catalyst for ammonia synthesis

被引：0
|
作者：
Muhler, M
Rosowski, F
Hinrichsen, O
Hornung, A
Ertl, G
机构：
来源：
11TH INTERNATIONAL CONGRESS ON CATALYSIS - 40TH ANNIVERSARY, PTS A AND B | 1996年 / 101卷
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暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Five Ru-based catalysts were prepared to study the effect of the support and the role of the alkali promoter in NH3 synthesis: Ru/Al2O3, Ru/MgO, Cs-Ru/Al2O3 and Cs(K)-Ru/MgO. The catalysts were characterized by N-2 physisorption, H-2 chemisorption and XPS. The absence of chlorine- and sulphur containing compounds turned out to be important for the preparation of highly active catalysts. Power law expressions were derived from conversion measurements at atmospheric pressure and at 20 bar. For all catalysts, the reaction order for H-2 was found to be negative suggesting that a P-N2 / P-H2 ratio in the feed gas higher than 1 / 3 would be favourable for industrial NH3 synthesis at high pressure. The microkinetic analysis of the temperature-programmed desorption and adsorption of N-2 and of the kinetics of isotopic exchange demonstrated the enhancing influence of the Cs promoter on the rate of N-2 dissociation and recombination. XPS measurements after thorough reduction revealed a shift of the Ru 3d(5/2) peak to lower binding energy by about 1 eV in the presence of Cs suggesting an electronic promoter effect.
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页码：317 / 326
页数：10
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