Electrochemical Aerobic Oxidative Cleavage of (sp3)C-C(sp3)/H Bonds in Alkylarenes

被引：11

作者：

Shen, Tong ^{[1
,2
]}

Liu, Shuai ^{[2
]}

Zhao, Jianyou ^{[1
]}

Wang, Nengyong ^{[1
]}

Yang, Le ^{[1
]}

Wu, Jintao ^{[1
]}

Shen, Xu ^{[1
]}

Liu, Zhong-Quan ^{[1
]}

机构：

[1] Nanjing Univ Chinese Med, Coll Pharm, Jiangsu Collaborat Innovat Ctr Chinese Med Resour, Nanjing 210023, Peoples R China

[2] Univ Bordeaux, Inst Mol Sci, F-33405 Talence, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 87卷 / 05期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-TRANSFER; CARBON; ACTIVATION; LIGHT; PALLADIUM; CHLORIDES; STRATEGY; ANILINES; ALKENES; CASCADE;

D O I：

10.1021/acs.joc.1c02947

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An electrochemistry-promoted oxidative cleavage of (sp(3))C-C(sp(3))/H bonds in alkylarenes was developed. Various aryl alkanes can be smoothly converted into ketones/aldehydes under aerobic conditions using a user-friendly undivided cell setup. The features of air as oxidant, scalability, and mild conditions make them attractive in synthetic organic chemistry.

引用

页码：3286 / 3295

页数：10

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