Liquid-liquid equilibrium and critical states for the quaternary system propionic acid-n-butanol-n-butyl propionate-water at 303.15 K

被引：15
|
作者：
Toikka, Maria [1 ]
Trofimova, Dariya [1 ]
Samarov, Artemiy [1 ]
机构：
[1] St Petersburg State Univ, Dept Chem Thermodynam & Kinet, Univ Skiy Prospect 26, St Petersburg 198504, Russia
来源：
FLUID PHASE EQUILIBRIA | 2018年 / 460卷
基金：
俄罗斯科学基金会;
关键词：
Liquid-liquid equilibrium; n-butyl propionate; Critical states; Cloud-point technique; ACETIC-ACID; ESTERIFICATION; MIXTURES; OIL; SOLUBILITY; 1-BUTANOL; CATALYST; ETHANOL; ESTERS;
D O I：
10.1016/j.fluid.2017.12.023
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
New experimental data on liquid-liquid equilibrium (LLE) and critical phases for the propionic acid nbutanol n-butyl propionate water system at 303.15 K and atmospheric pressure are presented. The LLE compositions were determined by gas chromatography, correlated and predicted by NRTL and UNIFAC models respectively. The results of NRTL and UNIFAC modelling are in sufficient agreement with experimental data. Standard deviations for binary and ternary subsystems do not exceed 0.79% (NRTL) and 5.1% (UNIFAC). In case of quaternary system investigated sigma(NRTL) = 0.56% and sigma(UNIFAC) = 2.2%. The study of critical states was carried out by "cloud-point technique" method. The run of critical curve in quaternary system was studied. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：17 / 22
页数：6
相关论文
共 50 条
  • [21] Excess Enthalpies and Heat of Esterification Reaction in Acetic Acid-n-Butanol-n-Butyl Acetate-Water System at 313.15 K
    Golikova, A. D.
    Anufrikov, Y. A.
    Shasherina, A. Y.
    Misikov, G. H.
    Toikka, M. A.
    Samarov, A. A.
    Toikka, A. M.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2024, 94 (SUPPL 1) : S177 - S183
  • [22] Liquid-liquid equilibrium for the quaternary system of o-xylene, water, butpic acid, and 1-Butanol at 298.15 K and atmospheric pressure
    Ok, Dong-Seok
    Kim, Young-Kyu
    Park, Dong-Won
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2007, 13 (03) : 352 - 359
  • [23] Liquid-Liquid Equilibria for the Quaternary System Water (1) + Acrylic Acid (2) + Acetic Acid (3) + Cyclohexane (4) at (293.15, 303.15, and 313.15) K
    Zhang, Hongxun
    Gong, Yanwen
    Li, Chen
    Zhang, Lei
    Zhu, Chunshan
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05): : 2332 - 2336
  • [24] Chemical equilibrium and liquid-liquid equilibrium in ternary mixtures of formaldehyde, water, and isobutanol/ n-butanol between 295 K and 348 K
    Winklbauer, Lukas
    Burger, Jakob
    FLUID PHASE EQUILIBRIA, 2025, 594
  • [25] Salt Effect on the Liquid-Liquid Equilibrium of (Water plus Propionic Acid plus Cyclohexanol) System at T=(298.2, 303.2, and 308.2) K
    Ghalami-Choobar, Bahram
    Ghanadzadeh, Ali
    Kousarimehr, Shahram
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2011, 19 (04) : 565 - 569
  • [26] Liquid-Liquid Equilibrium for the Ternary Systems Water+1-Butanol+1-Hexanol or 1-Octanol at 303.15, 313.15, and 323.15 K
    Zhang, Lili
    Yu, Yingmin
    Liao, Zhaohui
    Xu, Xiaosheng
    Huang, Xin
    Jia, Bing
    Li, Qingsong
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (02): : 477 - 486
  • [27] Liquid-liquid equilibrium measurements and interaction explorations for separation of azeotrope n-butyl acetate and n-butanol using three ionic liquids
    Wang, Dan
    Wei, Feng
    Reyes-Labarta, Juan A.
    Wang, Zhaojie
    Xu, Dongmei
    Gao, Jun
    Zhang, Lianzheng
    Wang, Yinglong
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 155
  • [28] Splitting of the liquid solution and the compositions of liquid phases in the water-n-propanol-n-propyl acetate system at 293.15, 303.15, and 313.15 K
    Toikka, M. A.
    Tsvetov, N. S.
    Toikka, A. M.
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2011, 45 (04) : 429 - 435
  • [29] Chemical equilibrium for the reactive system propionic acid plus ethanol plus ethyl propionate + water at 303.15 and 313.15 K
    Toikka, Maria
    Sadaeva, Anna
    Samarov, Artemiy
    Golikova, Alexandra
    Trofimova, Maya
    Shcherbakova, Nataliya
    Toikka, Alexander
    FLUID PHASE EQUILIBRIA, 2017, 451 : 91 - 95
  • [30] Liquid-liquid equilibrium of the ternary system water plus acetic acid plus sec-butyl acetate
    Hu, Song
    Chen, Qing-lin
    Zhang, Bing-jian
    Liang, Yuan-lan
    Gao, Xue-nong
    FLUID PHASE EQUILIBRIA, 2010, 293 (01) : 73 - 78
12345