Ionic Liquids as Catalyst for Synthesis of Some Aromatic Peracetylated N-(β-D-Glucopyranosyl)Thiosemicarbazones

被引：0
作者：
Nguyen Dinh Thanh [1 ]
Le The Hoai [1 ]
Nguyen Thi Kim Giang [2 ]
Nguyen Van Quoc [3 ]
机构：
[1] Vietnam Natl Univ, VNU Univ Sci, Fac Chem, 19 Le Thanh Tong, Hanoi, Vietnam
[2] Minist Publ Secur, Gen Dept 4, Inst Biochem Technol & Profess Documents, 80 Tran Quoc Hoan, Hanoi, Vietnam
[3] Vinh Univ, Fac Chem, 182 Le Duan, Vinh City, Nghe An, Vietnam
来源：
CURRENT ORGANIC SYNTHESIS | 2016年 / 13卷 / 05期
关键词：
Acetophenones; benzaldehydes; D-glucose; ionic liquids; thiosemicarbazones; microwave-assisted synthesis; TEMPERATURE MOLTEN-SALTS; THIOSEMICARBAZONES; DERIVATIVES; SOLVENTS; BINDING; SYSTEM; GREEN;
D O I：
10.2174/1570179413999151211115314
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Some acidic functionalized ionic liquids were evaluated for catalytic properties in synthetic reaction of peracetylated thiosemicarbazones having D-glucose moiety. For the first time, the ionic liquid, namely, 2-hydroxyethylammonium acetate proved to be an efficient, environment-friendly and easy catalyst for synthesis of these thiosemicarbazones in water as solvent under microwave irradiation, with high yields. The greener feature was found to be fairly general and the aqueous reaction media was reused in subsequent reactions with consistent activity. A series of N-(tetra-O-acetyl-beta-D-glucopyranosyl)thiosemicarbazones of substituted acetophenones and benzaldehydes have been synthesized based on these investigated results.
引用
收藏
页码：767 / 774
页数：8
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