Photovoltaic effect in a wide-area semiconductor-ferroelectric device

被引:30
作者
Katiyar, R. K. [1 ,2 ]
Kumar, A. [1 ,2 ]
Morell, G. [1 ,2 ]
Scott, J. F. [1 ,2 ,3 ]
Katiyar, R. S. [1 ,2 ]
机构
[1] Univ Puerto Rico, Dept Phys, San Juan, PR 00931 USA
[2] Univ Puerto Rico, Inst Funct Nanomat, San Juan, PR 00931 USA
[3] Univ Cambridge, Dept Phys, Cavendish Lab, Cambridge CB3 0HE, England
基金
美国国家科学基金会;
关键词
THIN-FILM; CERAMICS; BIFEO3;
D O I
10.1063/1.3628318
中图分类号
O59 [应用物理学];
学科分类号
摘要
Millimeter-diameter planar devices of glass/ZnO:Al/BiFeO(3)/La(0.67)Sr(0.33)CoO(3) (LSCO) heterostructures were fabricated by pulsed laser deposition (PLD) techniques. Diode-like behavior with high short-circuit current (SSC similar to 4 mA/cm(2)) and open-circuit voltage (OCV similar to 0.22 V) was obtained under the illumination of about 1% of maximum solar energy. Impedance spectroscopy revealed that electrode/dielectric interface and grain-boundary conduction are mainly responsible for the photo-current. Electrode/dielectric interface, grain boundary impedance, and low-frequency ac conductivity change by almost three orders of magnitude under weak light. Relaxation time of the photo-carriers changes from 80 ms to 96 mu s suggesting that with optimal collecting instruments, one should expect currents several orders higher. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3628318]
引用
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页数:3
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