Coordination polymers derived from alkali metal complexes of redox-active ligands

被引：5

作者：

Bazyakina, Natalia L. ^{[1
]}

Moskalev, Mikhail, V ^{[1
]}

Cherkasov, Anton, V ^{[1
]}

Makarov, Valentin M. ^{[1
]}

Fedushkin, Igor L. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Tropinina Str 49, Nizhnii Novgorod 603950, Russia

来源：

CRYSTENGCOMM | 2022年 / 24卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; SODIUM METAL; LITHIUM; CHEMISTRY; REDUCTION; MONOANION; NETWORKS; DIANION; LI;

D O I：

10.1039/d1ce01698a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of toluene solutions of (dpp-bian)M (dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene; M = Li, Na, K) with 4,4'-bipyridine (4,4'-bipy) affords coordination polymers [(dpp-bian)Li(4,4'-bipy)](n) (1), [(dpp-bian)Na(4,4'-bipy)(2)](n) (2) and [(dpp-bian)K(4,4'-bipy)](n) (3). Compounds 1-3 have been characterized by elemental analysis and thermogravimetry (TGA) as well as IR, UV-vis and ESR spectroscopy. According to single crystal X-ray analysis, products 1 and 2 present 1D coordination polymers, while product 3 reveals a 2D architecture.

引用

页码：2297 / 2304

页数：8

共 49 条

[1] Chemistry and applications of s-block metal-organic frameworks [J].

Alnaqbi, Mohamed A. ;

Alzamly, Ahmed ;

Ahmed, Salwa Hussein ;

Bakiro, Maram ;

Kegere, James ;

Nguyen, Ha L. .

JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (07) :3828-3854

[2] Recent Advances in s-Block Metal Carboxylate Networks [J].

Banerjee, Debasis ;

Parise, John B. .

CRYSTAL GROWTH & DESIGN, 2011, 11 (10) :4704-4720

[3] Solvothermal Synthesis and Structural Characterization of Ultralight Metal Coordination Networks [J].

Banerjee, Debasis ;

Kim, Sun Jin ;

Borkowski, Lauren A. ;

Xu, Wenqian ;

Parise, John B. .

CRYSTAL GROWTH & DESIGN, 2010, 10 (02) :709-715

[4] Crystal porosity and the burden of proof [J].

Barbour, LJ .

CHEMICAL COMMUNICATIONS, 2006, (11) :1163-1168

[5] Metal-Organic Frameworks Derived from Calcium and Strontium Complexes of a Redox-Active Ligand [J].

Bazyakina, Natalia L. ;

Makarov, Valentin M. ;

Ketkov, Sergey Yu ;

Bogomyakov, Artem S. ;

Rumyantcev, Roman, V ;

Ovcharenko, Victor, I ;

Fedushkin, Igor L. .

INORGANIC CHEMISTRY, 2021, 60 (05) :3238-3248

[6]

Bruker, 2018, SMART APEX3

[7]

Cai P, 2019, COMPREHENSIVE NANOSC

[8] Redox-active metal-organic frameworks for energy conversion and storage [J].

Calbo, Joaquin ;

Golomb, Matthias J. ;

Walsh, Aron .

JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (28) :16571-16597

[9] Salt forms of sulfadiazine with alkali metal and organic cations [J].

Campbell, Gemma ;

Fisher, Rebecca ;

Kennedy, Alan R. ;

King, Nathan L. C. ;

Spiteri, Rebecca .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2018, 74 :472-+

[10] Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications [J].

Chakraborty, Gouri ;

Park, In-Hyeok ;

Medishetty, Raghavender ;

Vittal, Jagadese J. .

CHEMICAL REVIEWS, 2021, 121 (07) :3751-3891

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