Synthesis and Crystal Structure of a Dinuclear Complex of Cu(II) with Tetra(3,5-diphenyl pyrazole)

被引：0

作者：

Zhu Wan-Ren ^{[1
]}

Ding Shu-Hong ^{[1
]}

Li Jia-Gui ^{[1
]}

Chen Yuan ^{[1
]}

Liu Guo-Cong ^{[1
]}

Zhu Yu-Lin ^{[1
]}

Huang Zhao-Yu ^{[1
]}

机构：

[1] Yulin Normal Univ, Sch Chem & Mat Sci, Yulin 537000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 08期

关键词：

complex; crystal Structure; pyrazole; characterization;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Cu(II) complex of tetra(3,5-diphenyl pyrazole) [Cu(C(15)H(12)N(2))(2)Cl(2)](2) (1) was syn-thesized, and its structure was determined by single-crystal X-ray diffraction and further characterized by elemental analysis, NMR and IR. 1 belongs to the monoclinic system, space group P2(1)/c with a = 13.3780(5), b = 15.1392(6), c = 15.5923(6) angstrom, beta = 124.522(2)degrees, Z = 2 and V = 2601.86(17) angstrom(3). In 1, each Cu(2+) ion is coordinated with two N atoms from two tetra(3,5-diphenyl pyrazole) ligands and three Cl(-) anions to give a distorted square-pyramidal geometry, which is further linked through edge-sharing bridging by Cl(-) anions to form a centrosymmetric dinuclear structure.

引用

页码：1101 / 1104

页数：4