Synthesis, characterization and photoelectric properties of a novel carbazole-containing Re(I) complex

被引：0
|
作者：
Sun, M
Xin, H
Zhang, YA
Wang, KZ [1 ]
Jin, LP
Huang, CH
机构：
[1] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
来源：
ACTA CHIMICA SINICA | 2003年 / 61卷 / 08期
关键词：
electroluminescence; rhenium complex; emission spectroscopy; photoelectric property;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel carbazole-containing Re(I) complex, Re(CO)(3)ClL (L = 1-ethyl-2-(N-ethyl-carbazol-4-yl) imidazo[4,5-f] 1, 10-phenanthroline), has been synthesized and characterized by elemental analysis, FT-IR, UV-vis, H-1 NMR and emission spectroscopy, and cyclic voltammetry. The double-layer electroluminescence device of ITO/TPD (30 nm)/Re(CO)(3)ClL (10 nm)/Mg0.9Ag0.1 (110 nm)/Ag (60 nm) fabricated by vacuum-deposition technique was found to emit bright orange-red light with a turn-on voltage of 5 V and a maximum luminance of 113 cd/m(2) at a bias voltage of 9 V.
引用
收藏
页码：1323 / 1325
页数：3
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