Highly Efficient Extraction of Sulfate Ions with a Tripodal Hexaurea Receptor

被引：169

作者：

Jia, Chuandong ^{[2
,4
]}

Wu, Biao ^{[1
]}

Li, Shaoguang ^{[2
,4
]}

Huang, Xiaojuan ^{[2
]}

Zhao, Qilong ^{[2
,4
]}

Li, Qian-Shu ^{[3
]}

Yang, Xiao-Juan ^{[2
]}

机构：

[1] NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China

[2] CAS, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China

[3] S China Normal Univ, Ctr Computat Quantum Chem, Guangzhou 510631, Guangdong, Peoples R China

[4] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期

基金：

中国国家自然科学基金;

关键词：

anion recognition; chelate effect; host-guest chemistry; hydrophobic effect; receptors; ANION-BINDING; SOLID-STATE; COORDINATION; CAPSULES; DESIGN; RECOGNITION; SELECTIVITY; MACROCYCLE; PROTEIN;

D O I：

10.1002/anie.201004461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fatal extraction: The Hofmeister bias for sulfate ions in aqueous environments can be overcome by using a tripodal hexaurea receptor (L) that completely encapsulates the sulfate ion in a complementary cavity protected by hydrophobic aromatic rings (see picture; C-gray, N-blue, O-red, S-yellow). Almost quantitative extraction of sulfate ions from an aqueous to an organic phase is achieved when this receptor is used as a liquid-liquid extractant. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：486 / 490

页数：5

共 38 条

[1] Anion receptors that contain metals as structural units [J].

Amendola, Valeria ;

Fabbrizzi, Luigi .

CHEMICAL COMMUNICATIONS, 2009, (05) :513-531

[2] Alfred Werner revisited: The coordination chemistry of anions [J].

Bowman-James, K .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :671-678

[3] Anion-binding modes in a macrocyclic amidourea [J].

Brooks, Simon J. ;

Gale, Philip A. ;

Light, Mark E. .

CHEMICAL COMMUNICATIONS, 2006, (41) :4344-4346

[4] Anion receptor chemistry: highlights from 2007 [J].

Caltagirone, Claudia ;

Gale, Philip A. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (02) :520-563

[5] 1,3-Diindolylureas and 1,3-Diindolythioureas: Anion Complexation studies in Solution and the Solid State [J].

Caltagirone, Claudia ;

Hiscock, Jennifer R. ;

Hursthouse, Michael B. ;

Light, Mark E. ;

Gale, Philip A. .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (33) :10236-10243

[6] Oligoindole-based foldamers with a helical conformation induced by chloride [J].

Chang, KJ ;

Kang, BN ;

Lee, MH ;

Jeong, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) :12214-12215

[7] A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups [J].

Custelcean, R ;

Moyer, BA ;

Hay, BP .

CHEMICAL COMMUNICATIONS, 2005, (48) :5971-5973

[8]

Custelcean R., 2008, ANGEW CHEM, V120, P1892

[9] Sulfate recognition by persistent crystalline capsules with rigidified hydrogen-bonding cavities [J].

Custelcean, Radu ;

Remy, Priscilla ;

Bonnesen, Peter V. ;

Jiang, De-En ;

Moyer, Bruce A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (10) :1866-1870

[10] Selectivity Principles in Anion Separation by Crystallization of Hydrogen-Bonding Capsules [J].

Custelcean, Radu ;

Bock, Aurelien ;

Moyer, Bruce A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (20) :7177-7185

← 1 2 3 4 →