Synthesis of polydendate acyclic and macrocyclic polyamine ligands bearing 2,2′-bipyridine or 2,2′-bipyridine N,N′-dioxide moieties

被引：0

作者：

Ziessel, R ^{[1
]}

Hissler, M ^{[1
]}

Ulrich, G ^{[1
]}

机构：

[1] Univ Strasbourg 1, Lab Chim Elect & Photon Mol, UPRESA 7008 CNRS, Ecole Chim Polymeres Mat,ECPM, F-67008 Strasbourg, France

来源：

SYNTHESIS-STUTTGART | 1998年 / 09期

关键词：

podands; oligopyridines; multitopic ligands; iron complexes;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of various acyclic and macrocyclic complexing agents bearing bipyridine or bipyridine N,N'-dioxide substituents is reported. These ligands, which possess three, four, or six pendant units, have been prepared by a general synthetic protocol starting from the mono(bromomethyl)-2,2'-bipyridine or mono(bromomethyl)-2,2'-bipyridine N,Ar-dioxide derivatives and the corresponding amine in the presence of a mineral base. NMR and FAB-MS spectral data indicate that tripode 5 and hexapode 9, respectively, form stable, highly colored acid redox-active mono-and diiron(II) complexes.

引用

页码：1339 / 1346

页数：8

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