An al K-edge EXAFS study of MoO3/H-ZSM-5 catalyst precursors

被引:4
作者
Burns, S.
Hargreaves, J. S. J.
Stockenhuber, M.
Wells, R. P. K.
机构
[1] Nottingham Trent Univ, Sch Biomed & Mol Sci, Catalysis & Nansci Lab, Nottingham NG11 8NS, England
[2] Univ Aberdeen, Dept Chem, Surface Chem & Catalysis Grp, Aberdeen AB24 EUE, Scotland
关键词
AlK-edge EXAFS; FTIR; NH3; TPD; MoO3; H-ZSM-5; acidity; methane dehydroaromatisation; MAS NMR;
D O I
10.1016/j.micromeso.2007.01.019
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A study of the activation of MoO3/H-ZSM-5 precursors for dehydroaromatisation of methane catalysts has been made. Using A1 K-edge EXAFS in conjunction with Al-27 MAS NMR, it can be seen that there is a significant distortion of the framework A1 environment, with respect to that in H-ZSM-5. In-situ FTIR studies confirm that molybdenum remains in the +VI oxidation state under the conditions employed in the EXAFS experiments, and that the acidity displayed by such precursors is exclusively of Bronsted type. Ammonia TPD experiments demonstrate that the presence of molybdenum oxo species leads to a reduction in the average Bronsted acid site strength. Crown Copyright (c) 2007 Published by Elsevier Inc. All rights reserved.
引用
收藏
页码:97 / 102
页数:6
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