High valent FeIV chemistry in sustainable oxidation catalysis

被引：20

作者：

Chandrachud, Preeti P. ^{[1
]}

Jenkins, David M. ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 19期

基金：

美国国家科学基金会;

关键词：

Iron; Catalysis; Green chemistry; Oxidation; PEPTIDE COUPLING REAGENTS; NONHEME IRON CATALYSTS; C-H BONDS; N-DEALKYLATION; ARYL AZIDES; SPECTROSCOPIC CHARACTERIZATION; PORPHYRIN COMPLEXES; CIS-DIHYDROXYLATION; ALKENE EPOXIDATION; ATOM-TRANSFER;

D O I：

10.1016/j.tetlet.2015.03.110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent research in oxidation catalysis has focused on employing first-row metals with a lower environmental impact than their traditional counterparts. Iron is particularly suited for this task since the discovery of isolable non-heme iron(IV) complexes over a decade ago. This Letter summarizes the developments in the last decade for oxidation of organic substrates that proceed through iron(IV) intermediates. Eight separate oxidation reactions are reviewed. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：2369 / 2376

页数：8

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