Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production

被引：26

作者：

Creasey, Julia J. ^{[1
]}

Parlett, Christopher M. A. ^{[2
]}

Manayil, Jinesh C. ^{[2
]}

Isaacs, Mark A. ^{[2
]}

Wilson, K. ^{[2
]}

Lee, Adam F. ^{[2
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] Aston Univ, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England

来源：

GREEN CHEMISTRY | 2015年 / 17卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

BIODIESEL SYNTHESIS; TRIGLYCERIDE TRANSESTERIFICATION; DOUBLE HYDROXIDES; ALUMINA; SBA-15; FUEL; PERSPECTIVE; RESOURCE; BIOFUELS; SILICAS;

D O I：

10.1039/c4gc01689k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.

引用

页码：2398 / 2405

页数：8

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