catena-Poly[[[diaquacadmium(II)]-bis[μ-3,5-bis(isonicotinamido)benzoato]] tetra-hydrate]

被引：0

作者：

Chen, Man-Sheng ^{[1
]}

Deng, Yi-Fang ^{[1
]}

Zhang, Chun-Hua ^{[1
]}

Kuang, Dai-Zhi ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MOLECULES; CHEMISTRY; SORPTION; DESIGN; CHAIN; BOND;

D O I：

10.1107/S1600536810036147

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, {[Cd(C19H13N4O4)(2)(H2O)(2)]center dot 4H(2)O}(n) or {[Cd(BBA)(2)(H2O)(2)]center dot 4H(2)O}(n), where BBA is 3,5-bis(isonicotinamido) benzoate, is isotypic with its Mn isologue [Chen et al. (2009). J. Coord. Chem. 62, 2421-2428]. The cation sits on a twofold axis and is six-coordinated in a slightly distorted octahedral geometry; the polyhedra are linked into zigzag chains, which are further connected by N-H center dot center dot center dot O, O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds as well as pi-pi interactions [centroid-centroid distance of 3.639 (2) angstrom], giving a three-dimensional supramolecular framework.

引用

页码：M1253 / U802

页数：13

共 17 条

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