Chemisorption of acetone on carbon nanotubes

被引：113

作者：

Chakrapani, N ^{[1
]}

Zhang, YMM

Nayak, SK

Moore, JA

Carroll, DL

Choi, YY

Ajayan, PM

机构：

[1] Rensselaer Polytech Inst, Dept Mat Sci & Engn, Troy, NY 12180 USA

[2] Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, Troy, NY 12180 USA

[3] Rensselaer Polytech Inst, Dept Chem, Troy, NY 12180 USA

[4] Clemson Univ, Dept Phys & Astron, Clemson, SC 29634 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2003年 / 107卷 / 35期

关键词：

D O I：

10.1021/jp034970v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Temperature-programmed desorption experiments show that acetone chemisorbs on nanotubes while physisorption occurs on graphite. Computed high binding energies for chemisorption using hybrid quantum mechanical and semiempirical calculations are in good agreement with the experimental thermal desorption data. The strong chemical interactions between acetone and the nanotube surface are established as being due to the effects of curvature and topological defects.

引用

页码：9308 / 9311

页数：4

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