From synthetic organic chemistry to electrochemistry

被引:9
作者
Lund, Henning [1 ]
机构
[1] Univ Aarhus, Dept Chem, DK-8000 Aarhus C, Denmark
关键词
Oxidations; Azomethine compounds; Heterocycles; Electrocatalysis; Electron transfer; Potentials of radicals; SINGLE-ELECTRON-TRANSFER; RATE-DETERMINING STEP; ELECTROORGANIC PREPARATIONS; STANDARD POTENTIALS; RADICAL-ANION; TERT-BUTYLATION; REDUCTION; POLAROGRAPHY; REAGENTS; HALIDES;
D O I
10.1007/s10008-010-1265-8
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The paper describes the change of the author's research from synthetic organic chemistry to electrochemistry and the advantages and disadvantages of having been trained in organic synthesis rather than in electrochemistry. The described research in electrochemistry includes, among other projects, oxidations in non-aqueous solvents, reduction of azomethine derivatives and heterocyclic compounds, synthesis of heterocyclic compounds, reduction of graphite, electrocatalytic reductions, electron transfer in nucleophilic substitutions and additions, determination of redox potentials of short-lived radicals, and electrochemical formation of Grignard compounds having reducible groups. At the end, some considerations after 60 years of research are included.
引用
收藏
页码:1733 / 1751
页数:19
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