Chalcogenide metal centers for oxygen reduction reaction: Activity and tolerance

被引：107

作者：

Feng, Yongjun ^{[1
]}

Gago, Aldo ^{[1
]}

Timperman, Laure ^{[1
]}

Alonso-Vante, Nicolas ^{[1
]}

机构：

[1] Univ Poitiers, Lab Electrocatalysis, CNRS, UMR 6503, F-86022 Poitiers, France

来源：

ELECTROCHIMICA ACTA | 2011年 / 56卷 / 03期

关键词：

Chalcogenides; Non-platinum; Oxygen reduction reaction; Tolerance; Fuel cells; METHANOL FUEL-CELL; RING-DISK ELECTRODE; SUPPORTED COSE2 NANOPARTICLES; MIXED-REACTANT; IN-SITU; CATHODE CATALYST; TUNGSTEN-OXIDE; THIN-FILMS; RU-SE; ELECTROCATALYTIC PROPERTIES;

D O I：

10.1016/j.electacta.2010.09.085

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This mini-review summarizes materials design methods, oxygen reduction kinetics, tolerance to small organic molecules and fuel cell performance of chalcogenide metal catalysts, particularly, ruthenium (RuxSey) and non-precious transition metals (MxXy: M = Co, Fe and Ni; X = Se and S). These non-platinum catalysts are potential alternatives to Pt-based catalysts because of their comparable catalytic activity (RuxSey), low cost, high abundance and. in particular, a high tolerance to small organic molecules. Developing trends of synthesis methods, mechanism of oxygen reduction reaction and applications in direct alcohol fuel cells as well as the substrate effect are highlighted. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1009 / 1022

页数：14

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