Effect of the substitution of Si for B on thermal stability, magnetic properties and corrosion resistance in novel Fe-rich amorphous soft magnetic alloy

被引:19
作者
Fan, Yanzhou [1 ]
Zhang, Suo [1 ]
Xu, Xiaofei [2 ]
Miao, Jiakai [1 ]
Zhang, Weiwei [1 ]
Wang, Tan [1 ]
Chen, Chen [1 ]
Wei, Ran [1 ]
Li, Fushan [1 ]
机构
[1] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China
[2] Henan Zhongyue Amorphous New Mat Co Ltd, Zhengzhou 452470, Peoples R China
基金
中国国家自然科学基金;
关键词
Fe-based amorphous alloys; Magnetic properties; Thermal stability; Corrosion resistance; BULK METALLIC GLASSES; HIGH SATURATION MAGNETIZATION; FORMING ABILITY; CRYSTALLIZATION; BEHAVIOR;
D O I
10.1016/j.intermet.2021.107306
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Soft magnetic alloy Fe83.3SixB16-xCu0.7 (x = 0, 1, 2, 3 and 4) ribbons were produced by the single roller melt spinning method. The Si content dependence of magnetic properties and corrosion resistance was investigated. Appropriate addition of Si is effective to the improvement of thermal stability, soft magnetic properties and corrosion resistance in this alloy system. Excellent soft magnetic properties with low coercivity 3.1 A/m and high magnetic flux density 1.66 T can be obtained when x = 1 annealed at 365 degrees C for 10 min. Compared with the Sifree ribbon, the corrosion resistance of the x = 1 alloy ribbon is also improved. The X-ray photoelectron spectroscopy (XPS) indicates that the formation of an SiO2-enriched passive film is mainly responsible for the high corrosion resistance of Si-containing (x = 1) alloy in 3.5 wt% NaCl solution. Low cost of raw materials, high thermal stability, good soft magnetic properties as well as excellent corrosion resistance make this alloy a promising candidate for future application.
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页数:7
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