A traceless, one-pot preparation of unsymmetric disulfides from symmetric disulfides through a repeated process involving sulfenic acid and thiosulfinate intermediates

被引：27

作者：

Han, Minsoo ^{[1
]}

Lee, Jong Tak ^{[1
]}

Hahn, Hoh-Gyu ^{[1
]}

机构：

[1] Korea Inst Sci & Technol, Organ Chem Lab, Seoul 136791, South Korea

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 02期

关键词：

Unsymmetric disulfide; Thiosulfinate; Sulfenic acid; PHENYL BENZENETHIOLSULFINATE; ORGANOSULFUR CHEMISTRY; CONVENIENT SYNTHESIS; EXCHANGE-REACTION; BOND FORMATION; THIOLS; OXIDATION; AGENTS; ALKYL;

D O I：

10.1016/j.tetlet.2010.11.042

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variable group of unsymmetric disulfides was prepared under mild reaction conditions and in high yields through the reaction of symmetric disulfides with sulfuryl chloride followed by treatment with thiols in the presence of water. (C) 2010 Published by Elsevier Ltd.

引用

页码：236 / 239

页数：4

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