Application of ionic liquids and deep eutectic solvents in biodiesel production: A review

被引：187

作者：

Troter, Dragan Z. ^{[1
]}

Todorovic, Zoran B. ^{[1
]}

Dokic-Stojanovic, Dusica R. ^{[1
,2
]}

Stamenkovic, Olivera S. ^{[1
]}

Veljkovic, Vlada B. ^{[1
]}

机构：

[1] Univ Nis, Fac Technol, Bulevar Oslobodenja 124, Leskovac 16000, Serbia

[2] Zdravlje Actavis, Vlajkova 199, Leskovac 16000, Serbia

来源：

RENEWABLE & SUSTAINABLE ENERGY REVIEWS | 2016年 / 61卷

关键词：

Biodiesel; Catalyst; Cosolvent; Deep eutectic solvent; Purification; AQUEOUS BIPHASIC SYSTEMS; FREE FATTY-ACIDS; OLEIC-ACID; LIPID EXTRACTION; SOYBEAN OIL; SEED OIL; FUNCTIONALIZED IMIDAZOLIUM; ENZYMATIC PRODUCTION; CATALYZED PRODUCTION; ASSISTED EXTRACTION;

D O I：

10.1016/j.rser.2016.04.011

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Developing technologies for the production of alternative fuels from biorenewable resources is a field of interest for many researchers. Adequate substitute to diesel fuel is biodiesel that is synthesized through the transesterification of vegetable oils or animal fats and fulfilled the international standards. Ionic liquids (ILs) and deep eutectic solvents (DESs) have gained tremendous attention for their use in biodiesel production because of environmental benefits and process improvements. The present work overviews the use of ILs and DESs in the reaction and purification steps of biodiesel production processes where they are used as catalysts, cosolvents and extracting solvent. In addition, the possibilities of recycling and reusing of ILs and DESs are pointed out. Moreover, optimization and kinetic studies of biodiesel synthesis in the presence of ILs or DESs are discussed. The use of novel technologies combined with ILs or and DESs are also considered. Therefore, the present paper highlights the promising uses of ILs and DESs in biodiesel production in the future. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：473 / 500

页数：28

共 130 条

[1] Extraction of glycerol from biodiesel into a eutectic based ionic liquid [J].

Abbott, Andrew P. ;

Cullis, Paul M. ;

Gibson, Manda J. ;

Harris, Robert C. ;

Raven, Emma .

GREEN CHEMISTRY, 2007, 9 (08) :868-872

[2] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[3] Novel solvent properties of choline chloride/urea mixtures [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2003, (01) :70-71

[4] New multi-phase catalytic systems based on tin compounds active for vegetable oil transesterificaton reaction [J].

Abreu, FR ;

Alves, MB ;

Macêdo, CCS ;

Zara, LF ;

Suarez, PAZ .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 227 (1-2) :263-267

[5] Modified bentonite as catalyst for esterification of oleic acid and ethanol [J].

Aghabarari, Behzad ;

Dorostkar, Nasim .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (04) :1468-1473

[6] Esterification of fatty acids by new ionic liquids as acid catalysts [J].

Aghabarari, Behzad ;

Dorostkar, Nasim ;

Ghiaci, Mehran ;

Amini, Sajad Ghaed ;

Rahimi, Ebrahim ;

Martinez-Huerta, M. V. .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (02) :431-435

[7] Synthesis of biodiesel from Nigella sativa seed oil using surfactant-Bronsted acidic-combined ionic liquid as catalyst [J].

Aghabarari, Behzad ;

Dorostkar, Nasim ;

Martinez-Huerta, M. V. .

FUEL PROCESSING TECHNOLOGY, 2014, 118 :296-301

[8] Microalgae as a sustainable energy source for biodiesel production: A review [J].

Ahmad, A. L. ;

Yasin, N. H. Mat ;

Derek, C. J. C. ;

Lim, J. K. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (01) :584-593

[9]

[Anonymous], SCI WORLD J

[10]

[Anonymous], IONIC LIQUIDS BIOREF

← 1 2 3 4 5 6 7 8 9 10 →