H/D fragment ratio in Lyman-alpha photolysis of CH2D2

被引:20
作者
Heck, AJR [1 ]
Zare, RN [1 ]
Chandler, DW [1 ]
机构
[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
关键词
D O I
10.1063/1.471045
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photofragment imaging technique is used to study the formation of H and D in the photolysis of CH2D2. From the images different reaction channels are distinguished that lead to hydrogen fragments. For the channel that leads to hydrogen atoms concomitant with methyl fragments a H/D ratio of 3.5+/-0.6 is found. (C) 1996 American Institute of Physics.
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页码:3399 / 3402
页数:4
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