Energy distribution and local fluctuations in strongly coupled open quantum systems: The extended resonant level model

被引:36
作者
Ochoa, Maicol A. [1 ]
Bruch, Anton [2 ,3 ]
Nitzan, Abraham [1 ,4 ]
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19401 USA
[2] Free Univ Berlin, Dahlem Ctr Complex Quantum Syst, D-14195 Berlin, Germany
[3] Free Univ Berlin, Fachbereich Phys, D-14195 Berlin, Germany
[4] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel
基金
以色列科学基金会;
关键词
THERMODYNAMICS; CONDUCTION; DYNAMICS;
D O I
10.1103/PhysRevB.94.035420
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We study the energy distribution in the extended resonant level model at equilibrium. Previous investigations [Phys. Rev. B 89, 161306 (2014); 93, 115318 (2016)] have found, for a resonant electronic level interacting with a thermal free-electron wide-band bath, that the expectation value for the energy of the interacting subsystem can be correctly calculated by considering a symmetric splitting of the interaction Hamiltonian between the subsystem and the bath. However, the general implications of this approach were questioned [Phys. Rev. 13 92, 235440 (2015)]. Here, we show that, already at equilibrium, such splitting fails to describe the energy fluctuations, as measured here by the second and third central moments (namely, width and skewness) of the energy distribution. Furthermore, we find that when the wide-band approximation does not hold, no splitting of the system-bath interaction can describe the system thermodynamics. We conclude that in general no proper division subsystem of the Hamiltonian of the composite system can account for the energy distribution of the subsystem. This also implies that the thermodynamic effects due to local changes in the subsystem cannot in general be described by such splitting.
引用
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页数:7
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