Synthesis of natural products by rhodium-mediated intramolecular C-H insertion

被引:0
作者
Taber, DF [1 ]
Stiriba, SE
机构
[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
[2] Univ Valencia, Dept Quim Inorgan, E-46100 Valencia, Spain
关键词
C-C coupling; cyclizations; diazo compounds; natural products; rhodium;
D O I
10.1002/(SICI)1521-3765(19980615)4:6<990::AID-CHEM990>3.0.CO;2-U
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rh-mediated intramolecular C-H insertion allows the direct construction of carbon - carbon bonds at previously unactivated centers. The natural product syntheses described here highlight the strategic advantages and efficiencies this reaction offers.
引用
收藏
页码:990 / 992
页数:3
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