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Miktoarm Star Polymers: Synthesis and Applications
被引:45
|作者:
Liu, Min
[1
]
Blankenship, Jacob R.
[2
]
Levi, Adam E.
[2
]
Fu, Qiang
[3
]
Hudson, Zachary M.
[1
]
Bates, Christopher M.
[2
,4
,5
]
机构:
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Univ Technol Sydney, Sch Civil & Environm Engn, Ultimo, NSW 2007, Australia
[4] Univ Calif Santa Barbara, Mat Dept, Mat Res Lab, Santa Barbara, CA 93106 USA
[5] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA
基金:
加拿大自然科学与工程研究理事会;
关键词:
RING-OPENING POLYMERIZATION;
TRANSFER RADICAL POLYMERIZATION;
STRONG THERMOPLASTIC ELASTOMERS;
FRAGMENTATION CHAIN TRANSFER;
RAFT POLYMERIZATION;
ELECTRON-TRANSFER;
BLOCK-COPOLYMERS;
HIGHLY EFFICIENT;
CROSS-LINKING;
CORE;
D O I:
10.1021/acs.chemmater.2c01220
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Polymers with precisely controlled structure and function are in high demand across a diverse array of applications spanning the life sciences and nanotechnology. One prototypical example is a class of branched block copolymers known as miktoarm stars (mu- stars), which contain two or more arm compositions connected at a common junction. Miktoarm stars have attracted considerable attention since their physical properties can be different from conventional linear block copolymers. This perspective highlights the latest developments and historical context in the field of miktoarm star polymers, including design strategies, synthetic techniques, and advanced characterization tools used to avoid common preparation pitfalls and tailor properties for emerging applications. Our contemporary perspective on mu-star polymer s is a resource for inspiring future research into this exciting class of materials at the intersection of chemistry, physics, and advanced technology.
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页码:6188 / 6209
页数:22
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