Solid polymer electrolytes based on cross-linked poly siloxane-δ-oligo(ethylene oxide):: ionic conductivity and electrochemical properties

被引：66
作者：
Kang, Y
Lee, W
Suh, DH
Lee, C
机构：
[1] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea
[2] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
来源：
JOURNAL OF POWER SOURCES | 2003年 / 119卷
关键词：
polymer electrolytes; lithium battery; PEO; polysiloxane; acrylate;
D O I：
10.1016/S0378-7753(03)00189-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Poly(siloxanes-g-oligo(ethylene oxide)) with acrylate groups at the terminal position were prepared and examined for the solid polymer electrolyte (SPE) by curing them. Poly(ethylene glycol) dimethyl ether (PEGDME) was added as a plasticizer. Conductivity of the resulting polymer electrolytes was greatly enhanced with increasing amounts of low molecular weight PEGDME. Maximum conductivity was found to be 8 x 10(-4) S/cm at 30 degreesC with an [EO]/[Li] ratio of about 8. These electrolytes showed oxidation stability up to 4.95 V against the lithium reference electrode. Reversible electrochemical plating/stripping of lithium was observed on the nickel electrode. The plating/stripping efficiency of lithium on nickel was measured to be about 53%. (C) 2003 Elsevier Science B.V All rights reserved.
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页码：448 / 453
页数：6
相关论文
共 24 条
[1]   Highly conductive PEO-like polymer electrolytes [J].
Abraham, KM ;
Jiang, Z ;
Carroll, B .
CHEMISTRY OF MATERIALS, 1997, 9 (09) :1978-1988
[2]   Synthesis of polyphosphazenes with ethyleneoxy-containing side groups: New solid electrolyte materials [J].
Allcock, HR ;
Kuharcik, SE ;
Reed, CS ;
Napierala, ME .
MACROMOLECULES, 1996, 29 (10) :3384-3389
[3]   Effect of oligo(ethyleneoxy)cyclotriphosphazenes, tetraglyme, and other small molecules on the ionic conductivity of the poly[bis(methoxyethoxyethoxy)phosphazene] (MEEP)/lithium triflate system [J].
Allcock, HR ;
Ravikiran, R ;
OConnor, SJM .
MACROMOLECULES, 1997, 30 (11) :3184-3190
[4]  
ALLCOCK HR, 1998, MACROMOLECULES, V31, P3384
[5]   FAST ION MOTION IN GLASSY AND AMORPHOUS MATERIALS [J].
ANGELL, CA .
SOLID STATE IONICS, 1983, 9-10 (DEC) :3-16
[6]   Composite polymer electrolytes with improved lithium metal electrode interfacial properties - I. Electrochemical properties of dry PEO-LiX systems [J].
Appetecchi, GB ;
Croce, F ;
Dautzenberg, G ;
Mastragostino, M ;
Ronci, F ;
Scrosati, B ;
Soavi, F ;
Zanelli, A ;
Alessandrini, F ;
Prosini, PP .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) :4126-4132
[7]  
Armand M. B., 1987, POLYM ELECTROLYTE RE, P1
[8]   Ultraviolet radiation curing of acrylates for lithium polymer electrolytes [J].
Choi, Y ;
Kim, SK ;
Chang, KH ;
Lee, MH .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (09) :1118-1121
[9]   Selection of new Kynar-based electrolytes for lithium-ion batteries [J].
Christie, AM ;
Christie, L ;
Vincent, CA .
JOURNAL OF POWER SOURCES, 1998, 74 (01) :77-86
[10]   Trends in polymer electrolytes for secondary lithium batteries [J].
Dias, FB ;
Plomp, L ;
Veldhuis, JBJ .
JOURNAL OF POWER SOURCES, 2000, 88 (02) :169-191
123