Crystal structures of [(CH3)2NH2]3InBr6 and [4-C1C5H4NH]2InBr5

被引：13

作者：

Ishihara, H

Dou, S

Gesing, TM

Paulus, H

Fuess, H

Weiss, A

机构：

[1] Saga Univ, Fac Culture & Educ, Saga 8408502, Japan

[2] Univ Hannover, Inst Mineral, D-30167 Hannover, Germany

[3] Tech Univ Darmstadt, Fachgebiet Strukturforsch, Fachbereich Mat Wissensch, D-64287 Darmstadt, Germany

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1998年 / 471卷 / 1-3期

关键词：

crystal structures; tris(dimethylammonium) hexabromoindate(III); bis(4-chloropyridinium) pentabromoindate(III);

D O I：

10.1016/S0022-2860(98)00444-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The crystal structures of tris(dimethylammonium) hexabromoindate(III) (1) and bis(4-chloropyridinium) pentabromoindate(III) (2) are determined, The structure of 1 consists of two kinds of isolated octahedral [InBr6](3-) anions; trigonal, R (3) over bar, Z = 12, a = 2895.8(9) and c = 828.2(3) pm. Compound 2 has an isolated distorted square pyramidal [InBr5](2-) anion; triclinic, P (1) over bar, Z = 2, a = 771.8(3), b = 907.5(4), and c = 1492.0(6) pm, alpha = 81.52(1), beta = 83.98(1), and gamma = 71.60(1)degrees. The five-coordinated In-III compound is very rare. The shapes of anions are compared with the results of MO calculations. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：175 / 182

页数：8

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