Influence of Solvent Evaporation Rate in the Preparation of Carbon-Coated Lithium Iron Phosphate Cathode Films on Battery Performance

被引：38

作者：

Goren, Attila ^{[1
,2
]}

Cintora-Juarez, Daniel ^{[3
]}

Martins, Pedro ^{[1
]}

Ferdov, Stanislav ^{[1
]}

Silva, Maria Manuela ^{[2
]}

Luis Tirado, Jose ^{[3
]}

Costa, Carlos M. ^{[1
,2
]}

Lanceros-Mendez, Senentxu ^{[1
]}

机构：

[1] Univ Minho, Ctr Dept Phys, Campus Gualtar, P-4710057 Braga, Portugal

[2] Univ Minho, Ctr Dept Chem, Campus Gualtar, P-4710057 Braga, Portugal

[3] Univ Cordoba, Lab Quim Inorgan, Edificio Maria Curie Campis Rabanales, Cordoba 14071, Spain

来源：

ENERGY TECHNOLOGY | 2016年 / 4卷 / 05期

关键词：

carbon; electrochemistry; lithium; iron; thin films; LI-ION BATTERIES; ELECTROCHEMICAL PROPERTIES; LIFEPO4; CATHODE; POLY(VINYLIDENE FLUORIDE); COMPOSITE ELECTRODES; POLYACRYLIC-ACID; HIGH-CAPACITY; BINDER; MORPHOLOGY; STABILITY;

D O I：

10.1002/ente.201500392

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this work, the drying step for cathodes based on carbon-coated LiFePO4 prepared in the temperature range of 60-120 degrees C has been investigated in detail. The microstructure of the cathode shows a homogeneous distribution of the active material and conductive additive particles independent of the drying temperature. However, the results of impedance spectroscopy and cycling voltammetry are affected by the drying temperature. The solvent evaporation temperature, therefore, affects the polymer binder distribution and its characteristics, which include the polar phase content of the polymer and its affinity with the other components of the cathode. The discharge capacity value after 50 cycles is 120 and 81 mAhg(-1) for the samples dried at 80 and 60 degrees C, respectively, which show the best and worst battery performance, respectively. It was concluded that carbon-coated LiFePO4 cathodes should be prepared at drying temperatures between 80 and 100 degrees C for optimized performance.

引用

页码：573 / 582

页数：10

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