Facile fabrication of manganese phosphate nanosheets for supercapacitor applications

被引:53
作者
Dai, Yan-Hua [1 ]
Kong, Ling-Bin [1 ,2 ]
Yan, Kun [1 ]
Shi, Ming [1 ]
Luo, Yong-Chun [2 ]
Kang, Long [2 ]
机构
[1] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
[2] Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China
基金
中国国家自然科学基金;
关键词
Manganese phosphate nanosheets; Chemical precipitation method; Anneal; Capacitances; HIGH-PERFORMANCE; ELECTRODE MATERIALS; ULTRATHIN NANOSHEETS; MNO2; GRAPHENE; NANOSTRUCTURES; NANORODS; ARRAYS;
D O I
10.1007/s11581-016-1652-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Manganese phosphate (Mn-3(PO4)(2)center dot 3H(2)O) nanosheets are successfully fabricated via a facile chemical precipitation method. The Mn-3(PO4)(2)center dot 3H(2)O nanosheets synthesized at 70 A degrees C show excellent supercapacitive performance in 2 M KOH alkaline electrolyte. Typical pseudocapacitance feature of Mn-3(PO4)(2)center dot 3H(2)O nanosheets treated at various annealing temperatures is then evaluated in 2 M KOH alkaline electrolyte. M-3 annealed at 750 A degrees C exhibits the optimal integrated electrochemical properties. Furthermore, an asymmetric supercapacitor composed of M-3 as positive electrode and activated carbon (AC) as negative electrode can reach the high-voltage region of 0-1.7 V. The asymmetric supercapacitor displays high energy density of 32.32 Wh kg(-1) and power density of 4250 W kg(-1). The impressive results presented here may pave the way for promising applications in high energy density storage systems.
引用
收藏
页码:1461 / 1469
页数:9
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