Supramolecular assembly of well-separated, linear columns of closely-spaced C60 molecules facilitated by dipole induction

被引:37
作者
Barbour, LJ [1 ]
Orr, GW [1 ]
Atwood, JL [1 ]
机构
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
关键词
D O I
10.1039/a804419h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Go-crystallization of C-60 With p-bromocalix[4]arene propyl ether results in a remarkably well packed structure; the calixarene molecules pack with their dipole moments aligned unidirectionally and the unusually close van der Waals contact between the C-60 molecules is most likely a result of an opposing induced dipole.
引用
收藏
页码:1901 / 1902
页数:2
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