Synthesis of Metallophthalocyanine Covalent Organic Frameworks That Exhibit High Carrier Mobility and Photoconductivity

被引：487

作者：

Ding, Xuesong ^{[1
]}

Guo, Jia ^{[1
,4
]}

Feng, Xiao ^{[1
]}

Honsho, Yoshihito ^{[3
]}

Guo, Jingdong

Seki, Shu ^{[3
]}

Maitarad, Phornphimon ^{[1
]}

Saeki, Akinori ^{[3
]}

Nagase, Shigeru ^{[4
]}

Jiang, Donglin ^{[1
,2
]}

机构：

[1] Inst Mol Sci, Dept Mat Mol Sci, 5-1 Higashiyama, Okazaki, Aichi 4448787, Japan

[2] Japan Sci & Technol Agcy JST, Chiyoda Ku, Tokyo 1020075, Japan

[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[4] Natl Inst Nat Sci, Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 06期

关键词：

carrier transport; covalent organic frameworks; photoconduction; phthalocyanines; porous materials; TRIAZINE-BASED FRAMEWORKS; RETICULAR SYNTHESIS; HYDROGEN; CRYSTALLINE; STORAGE;

D O I：

10.1002/anie.201005919

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A light COF: Two-dimensional covalent organic frameworks of a nickel phthalocyanine have been synthesized. Owing to well-ordered stacking of the phthalocyanine units, the resulting 2D framework provides enhanced and broad light absorbance and facilitates charge transport. The material becomes highly photoconductive and is exceptionally sensitive to deep-red visible and near-infrared light. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1289 / 1293

页数：5

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