Butler-Volmer-Monod model for describing bio-anode polarization curves

被引：114

作者：

Hamelers, Hubertus V. M. ^{[1
]}

ter Heijne, Annemiek ^{[1
,2
]}

Stein, Nienke ^{[1
,2
]}

Rozendal, Rene A. ^{[3
]}

Buisman, Cees J. N. ^{[1
,2
]}

机构：

[1] Wageningen Univ, Subdept Environm Technol, NL-6700 EV Wageningen, Netherlands

[2] Agora, Ctr Excellence Sustainable Water Technol, Wetsus, NL-8900 CC Leeuwarden, Netherlands

[3] Univ Queensland, Adv Water Management Ctr, St Lucia, Qld 4072, Australia

来源：

BIORESOURCE TECHNOLOGY | 2011年 / 102卷 / 01期

关键词：

Bioelectrochemical system; Microbial Fuel Cell; Anode; Butler-Volmer; Monod; MICROBIAL FUEL-CELLS; RESPIRING BACTERIA; ELECTRON-TRANSFER; BIOFILM ANODE; PERFORMANCE; PROTEINS;

D O I：

10.1016/j.biortech.2010.06.156

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

A kinetic model of the bio-anode was developed based on a simple representation of the underlying biochemical conversions as described by enzyme kinetics, and electron transfer reactions as described by the Butler-Volmer electron transfer kinetics. This Butler-Volmer-Monod model was well able to describe the measured bio-anode polarization curves. The Butler-Volmer-Monod model was compared to the Nernst-Monod model described the experimental data significantly better. The Butler-Volmer-Monod model has the Nernst-Monod model as its full electrochemically reversible limit. Contrary to the Nernst-Monod model, the Butler-Volmer-Monod model predicts zero current at equilibrium potential. Besides, the Butler-Volmer-Monod model predicts that the apparent Monod constant is dependent on anode potential, which was supported by experimental results. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：381 / 387

页数：7

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