Orientation of para-phenylene crystals nucleated on alkali-halide stepped substrates

被引:3
作者
Yamamoto, H. [1 ]
Takahashi, H. [1 ]
Yano, N. [1 ]
Takagishi, Y. [1 ]
Kubo, T. [1 ]
Harami, T. [1 ]
Hondoh, H. [1 ]
Nakada, T. [1 ]
机构
[1] Ritsumeikan Univ, Fac Sci & Engn, Dept Phys Sci, Shiga 5258577, Japan
关键词
atomic force microscopy; crystal structure; diffusion; interfaces; nucleation; surface structures; graphoepitaxy; physical vapor deposition processes;
D O I
10.1016/j.jcrysgro.2007.11.129
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The influences of substrate steps on crystallographic orientation of para-quaterphenylene (p-4P) thin films deposited on potassium chloride (KCl) (001) cleaved in ultrahigh vacuum have been studied in needle-shaped crystals preferentially nucleated at the step edges of the substrates. Surprisingly, most of the crystals nucleated on the so-called tartan zone of the KCl (001) substrate did not grow epitaxially, but became aligned in the directions of the cleaved steps, indicating the onset of grapho-epitaxy. The effects of step height and width on the nucleation and growth of p-4P crystals have been discussed. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1729 / 1733
页数:5
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