Emerging Noble Metal Aerogels: State of the Art and a Look Forward

被引:115
作者
Du, Ran [1 ]
Fan, Xuelin [1 ]
Jin, Xinyi [1 ,2 ]
Huebner, Rene [3 ]
Hu, Yue [4 ]
Eychmueller, Alexander [1 ]
机构
[1] Tech Univ Dresden, Phys Chem, Bergstr 66b, D-01062 Dresden, Germany
[2] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
[3] Helmholtz Zentrum Dresden Rossendorf, Inst Ion Beam Phys & Mat Res, Bautzner Landstr 400, D-01328 Dresden, Germany
[4] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325000, Peoples R China
基金
中国国家自然科学基金;
关键词
HIGH-PERFORMANCE ELECTROCATALYST; BIMETALLIC AEROGELS; PD; NANOPARTICLES; GOLD; OXIDATION; AU; AGGREGATION; FABRICATION; EVOLUTION;
D O I
10.1016/j.matt.2019.05.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Noble metal aerogels (NMAs), as the most important class of noble metal foams (NMFs), appear as emerging functional porous materials in the field of materials science. Combining the irreplaceable roles of noble metals in certain scenarios, as well as monolithic and porous features of aerogels, NMAs can potentially revolutionize diverse fields, such as catalysis, plasmonics, and biology. Despite profound progress, grand challenges remain in their fabrication process, including the efficient structure control, the comprehensive understanding of the formation mechanisms, and the generality of the fabrication strategies, thus inevitably retarding the material design and optimization. This Perspective focuses on the key progress, especially of the fabrication strategies for NMAs during the last two decades, while other NMFs are also succinctly introduced. Challenges and opportunities are summarized to highlight the unexploited space and future directions in expectation of stimulating the broad interest of interdisciplinary scientists.
引用
收藏
页码:39 / 56
页数:18
相关论文
共 69 条
[1]   Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007) [J].
Aleman, J. ;
Chadwick, A. V. ;
He, J. ;
Hess, M. ;
Horie, K. ;
Jones, R. G. ;
Kratochvil, P. ;
Meisel, I. ;
Mita, I. ;
Moad, G. ;
Penczek, S. ;
Stepto, R. F. T. .
PURE AND APPLIED CHEMISTRY, 2007, 79 (10) :1801-1827
[2]  
[Anonymous], 2008, ANGEW CHEM
[3]   Diffusion limited cluster aggregation with irreversible slippery bonds [J].
Babu, S. ;
Gimel, J. C. ;
Nicolai, T. .
EUROPEAN PHYSICAL JOURNAL E, 2008, 27 (03) :297-308
[4]   Surface-chemistry-driven actuation in nanoporous gold [J].
Biener, J. ;
Wittstock, A. ;
Zepeda-Ruiz, L. A. ;
Biener, M. M. ;
Zielasek, V. ;
Kramer, D. ;
Viswanath, R. N. ;
Weissmueller, J. ;
Baeumer, M. ;
Hamza, A. V. .
NATURE MATERIALS, 2009, 8 (01) :47-51
[5]   Hydrogels and Aerogels from Noble Metal Nanoparticles [J].
Bigall, Nadja C. ;
Herrmann, Anne-Kristin ;
Vogel, Maria ;
Rose, Marcus ;
Simon, Paul ;
Carrillo-Cabrera, Wilder ;
Dorfs, Dirk ;
Kaskel, Stefan ;
Gaponik, Nikolai ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (51) :9731-9734
[6]   Direct solution-based reduction synthesis of Au, Pd, and Pt aerogels [J].
Burpo, Fred J. ;
Nagelli, Enoch A. ;
Morris, Lauren A. ;
McClure, Joshua P. ;
Ryu, Madeline Y. ;
Palmer, Jesse L. .
JOURNAL OF MATERIALS RESEARCH, 2017, 32 (22) :4153-4165
[7]   Core-Shell Structuring of Pure Metallic Aerogels towards Highly Efficient Platinum Utilization for the Oxygen Reduction Reaction [J].
Cai, Bin ;
Huebner, Rene ;
Sasaki, Kotaro ;
Zhang, Yuanzhe ;
Su, Dong ;
Ziegler, Christoph ;
Vukmirovic, Miomir B. ;
Rellinghaus, Bernd ;
Adzic, Radoslav R. ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (11) :2963-2966
[8]   Function-Led Design of Aerogels: Self-Assembly of Alloyed PdNi Hollow Nanospheres for Efficient Electrocatalysis [J].
Cai, Bin ;
Wen, Dan ;
Liu, Wei ;
Herrmann, Anne-Kristin ;
Benad, Albrecht ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (44) :13101-13105
[9]   A review on non-precious metal electrocatalysts for PEM fuel cells [J].
Chen, Zhongwei ;
Higgins, Drew ;
Yu, Aiping ;
Zhang, Lei ;
Zhang, Jiujun .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3167-3192
[10]   Porous three-dimensional network of Pd-Cu aerogel toward formic acid oxidation [J].
Douk, Abdollatif Shafaei ;
Farsadrooh, Majid ;
Damanigol, Farzane ;
Moghaddam, Alireza Ansari ;
Saravani, Hamideh ;
Noroozifar, Meissam .
RSC ADVANCES, 2018, 8 (42) :23539-23545