Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

被引：6

作者：

Ling, Irene ^{[1
,2
]}

Sobolev, Alexandre N. ^{[3
]}

Raston, Colin L. ^{[2
]}

机构：

[1] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Flinders Univ S Australia, Sch Chem & Phys Sci, Ctr NanoScale Sci & Technol, Bedford Pk, SA 5042, Australia

[3] Univ Western Australia, Sch Chem & Biochem, Crawley, WA 6009, Australia

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 07期

基金：

澳大利亚研究理事会;

关键词：

CRYSTAL SUPRAMOLECULAR MOTIFS; MULTIPLE PHENYL EMBRACES; LARGE ORGANIC IONS; AMINO-ACIDS; PH(4)P(+) CATIONS; COMPLEXES; TETRAPHENYLPHOSPHONIUM; CONFINEMENT; INTERPLAY; AMMONIUM;

D O I：

10.1039/c4ce02086c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solution mediated organization of p-sulfonatocalix[4] arene, benzyl-triphenylphosphonium cations, and bis(triethylammoniomethyl)-benzene dications in the solid state results in the ammonium dications preferentially binding in the cavities of two opposing calixarenes which take on a -3 charge, with the phosphonium cations arranged in a separate 2D sheet relative to the calixarene bilayer.

引用

页码：1526 / 1530

页数：5

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