Synthesis, Spectroscopic Studies and Structure of 2-[(Benzo[d]thiazol-2-ylamino)methyl]phenol

被引：0

作者：

Yildiz, Mustafa ^{[2
]}

Ozay, Hava ^{[2
]}

Unver, Huseyin ^{[1
]}

Iskeleli, Nazan Ocak ^{[3
]}

Zengin, D. Mehmet ^{[1
]}

Durlu, Tahsin Nuri ^{[1
]}

机构：

[1] Ankara Univ, Dept Phys, Fac Sci, TR-06100 Ankara, Turkey

[2] Canakkale Onsekiz Mart Univ, Dept Chem, Fac Sci & Arts, TR-17100 Canakkale, Turkey

[3] Ondokuz Mayis Univ, Dept Sci Educ, TR-55200 Atakum, Samsun, Turkey

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 11期

关键词：

Crystal structure; Spectroscopic studies; FT-IR; UV-visible; NMR; SCHIFF-BASES; ANTIMICROBIAL ACTIVITIES; CRYSTAL-STRUCTURES; TAUTOMERISM; COMPLEXES; THIAZOLE; LIGANDS;

D O I：

10.1007/s10870.010.9761.3

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Schiff base (E)-2-[(benzo[d]thiazol-2-ylimino)methyl]phenol (1) has been synthesized from the reaction of 2-hydroxy-benzaldehyde with 2-aminobenzothiazole The 2-[(benzo[d]thiazol-2-ylamino)methyl]phenol (2) was prepared reduction of the Schiff base 1 with sodium borohydride The compounds 1 and 2 have been characterized by elemental analysis, FT-IR, H-1-NMR, C-13-NMR and UV-visible spectroscopic techniques The structure of the compound 2 has also been examined crystallographically The compound 2 crystallizes in the monoclinic space group P2/c The unit cell parameters were found as a = 10 017(1), b = 11 725(1), c = 10 341(1) angstrom, V = 1208 1(1) A(3), D-x = 1 409 g cm(-3) and Z = 4 The crystal structure was solved by direct methods and refined by the full-matrix least squares method and found as R-1 = 0 0308 and wR(2) = 0 0818 for 2032 for the observed reflections [1 > 2 sigma(1)]

引用

页码：909 / 913

页数：5

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