Three-dimensional carbonaceous for potassium ion batteries anode to boost rate and cycle life performance

被引:56
作者
Du, Jincheng [1 ]
Gao, Shenshen [1 ]
Shi, Penghui [1 ,2 ,3 ]
Fan, Jinchen [1 ,2 ]
Xu, QunJie [1 ,2 ]
Min, YuLin [1 ,2 ]
机构
[1] Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China
[2] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
[3] Henan Prov Key Lab Water Pollut Control & Rehabil, Pingdingshan, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Potassium-ion batteries; Amorphous; Boost rate; Superabsorbent polymers; Energy storage; HIERARCHICALLY POROUS CARBON; LITHIUM AVAILABILITY; DOPED GRAPHENE; HARD CARBON; SODIUM; INTERCALATION; NANOTUBES; GRAPHITE; FABRICATION; ELECTRODES;
D O I
10.1016/j.jpowsour.2020.227727
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Potassium-ion batteries (KIBs) are considered to be better alternative to lithium-ion batteries due to its high energy density, stability and safety. However, the problems of fast capacity declining at longtime recycling and poor storage capacity prevent its practical use. In this study, we report the development of 3-dimensional (3D) carbonaceous for KIBs anode that boost rate and cycle life performance. A simple method for designing an amorphous 3D carbon material of KIBs anode with superabsorbent polymers (SAPs) stripped from the baby diaper was fabricated with higher efficiency and environmentally friend. The 3D SAP porous carbon material can be obtained by simple carbonization and reactivation. Electrochemical measurements show that, a reversible potassium storage capacity of 270.4 mAh g(-1) at the current density of 50 mA g(-1) after 100 cycles, which is higher specific capacity than those of the reported undoped carbon nanomaterials. At the same time, at a current density of 1000 mA g(-1), the electrode material also showed extremely excellent cycle stability with discharge capacity of 161.7 mAh g(-1) after 2000 cycles.
引用
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页数:10
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