Progress in nitrile-based polymer electrolytes for high performance lithium batteries

被引：321

作者：

Hu, Pu ^{[1
,2
]}

Chai, Jingchao ^{[1
,2
]}

Duan, Yulong ^{[1
]}

Liu, Zhihong ^{[1
]}

Cui, Guanglei ^{[1
]}

Chen, Liquan ^{[3
]}

机构：

[1] Chinese Acad Sci, Qingdao Ind Energy Storage Technol Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 26期

关键词：

HIGH IONIC-CONDUCTIVITY; GEL ELECTROLYTES; ELECTROCHEMICAL-BEHAVIOR; POLYACRYLONITRILE PAN; ETHYLENE CARBONATE; COMPOSITE; BLEND; SALT; POLY(ACRYLONITRILE); TRANSPORT;

D O I：

10.1039/c6ta02907h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrile or cyano-based compounds have aroused interest in high performance battery electrolyte fields due to their unique characteristics such as a high dielectric constant, high anodic oxidization potential and favorable interaction with lithium ions. Particularly, owing to the presence of a unique plastic-crystalline phase, succinonitrile/salt-based solid electrolytes possess an ultra high ionic conductivity of more than 10(-3) S cm(-1) at room temperature. Herein, recent progress in nitrile-based polymer electrolytes has been reviewed in terms of their potential application in flexible, solid-state or high voltage lithium batteries. Factors affecting the ionic conductivity of nitrile-based electrolytes have also been summarized. We hope that fresh and established researchers can obtain a clear perspective of nitrile based polymer electrolytes and our mini review can spur more extensive interest for the exploration of high performance batteries.

引用

页码：10070 / 10083

页数：14

共 104 条

[21] Influence of water and thermal history on ion transport in lithium salt-succinonitrile plastic crystalline electrolytes [J].