Cation-π Interactions in Organic Synthesis

被引：163
|
作者：
Yamada, Shinji [1 ]
机构：
[1] Ochanomizu Univ, Dept Chem, Fac Sci, Bunkyo Ku, 2-1-1 Otsuka, Tokyo 1128610, Japan
来源：
CHEMICAL REVIEWS | 2018年 / 118卷 / 23期
关键词：
DYNAMIC KINETIC RESOLUTION; SOLID-STATE PHOTODIMERIZATION; SPACE ELECTRONIC INTERACTIONS; TEMPLATE-DIRECTED SYNTHESIS; DIELS-ALDER REACTION; ZEOLITE NA-Y; CATALYTIC ENANTIOSELECTIVE SYNTHESIS; 9-SUBSTITUTED ACRIDIZINIUM SALTS; AMINO-AROMATIC INTERACTIONS; MEDIUM-SIZED CYCLOPHANES;
D O I：
10.1021/acs.chemrev.8b00377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The cation-pi interaction is an attractive noncovalent interaction between a cation and a pi system. Due to the stronger interaction energy than those of the other pi interactions, such as pi-pi and CH-pi interactions, the cation-pi interaction has recently been recognized as a new tool for controlling the regio- and stereoselectivities in various types of organic reactions. This review attempts to cover a variety of organic reactions controlled by cation-pi interactions, which includes not only recent examples but also those reported before the term "cation-pi interaction" was defined in 1990. This review will provide comprehensive knowledge on the role of cation it interactions in organic synthesis.
引用
收藏
页码：11353 / 11432
页数：80
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